Artigos de Revista

The Fundação Ricardo Espírito Santo Silva (FRESS) has the mission of defend, train, study, develop and implement Portuguese Fine Arts in Portugal. This paper reflects the process of Conservation-Restoration training, where students apply the most recent analytical techniques to the characterization of artwork towards enabling and supporting conservation intervention. In this study, the materials used to produce a 19th century sedan chair were characterised by optical microscopy, spectroscopic (SEM-EDS, ?-Raman and FTIR-imaging) and chromatographic (HPLC-DAD/MS) techniques. The use of natural and synthetic dyes was identified in textiles found inside the chair, including cochineal, brazilwood and fuchsine. Several paint layers with different colours and compounds, such as barite, calcium carbonate, lead white, hematite and Prussian blue, were identified in the external painted wood surface of the chair. The variety of identified materials, interspersed between layers of animal glue, reflects the different interventions that took place on the chair over time, supporting the intervention strategies reported/prescribed for the conservation-restoration procedure.

This paper deals with the application of building regulations to the rehabilitation of existing buildings, taking a recent Government initiative to deregulate construction works in existing buildings as a case-study. To contextualize the analysis, the Portuguese housing stock is briefly described and the way building regulations apply to existing buildings in Portugal is reviewed. The deregulation initiative was presented by the Portuguese Government as a pragmatic policy measure to stimulate urban rehabilitation but sparkled wide opposition from a number of professional and scientific associations, who questioned both its strategic sense and its technical convenience. The structural safety professional and scientific community was particularly active in this debate. Focusing on them, the analysis of the process shows that: i) the opposing positions were founded on two equally reasonable priorities (i.e., to stimulate the rehabilitation of existing building stock versus to improve structural safety), ii) both parties were unable to support their positions with hard facts and argued mostly around their respective priorities and iii) the debate ended in a deadlock. Main conclusions are that to overcome the deadlock more applied research is needed to bring forward appropriate solutions to rehabilitate existing buildings, along with a better dissemination of this practical knowledge in the building and real estate sectors. An informed and enlightened debate involving all relevant stakeholders, including the consumers

On line monitoring programs based on spectroscopy have a high application potential for the detection of hazardous wastewater discharges in sewer systems. Wastewater hydraulics poses a challenge for in situ spectroscopy, especially when the system includes storm water connections leading to rapid changes in water depth, velocity and in the water quality matrix. Thus, there is a need to optimize and fix the location of in situ instruments, limiting their availability for calibration. In this context, the development of calibration models on bench spectrophotometers, to estimate wastewater quality parameters from spectra acquired in in situ instruments, could be very useful. However, spectra contain information not only from the samples but also from the spectrophotometer, generally invalidating this approach. The use of calibration transfer methods is a promising solution to this problem. In this study, calibration models were developed using interval partial least squares (iPLS), for the estimation of total suspended solids (TSS) and chemical oxygen demand (COD) in sewage from ultraviolet-visible spectra acquired in a bench scanning spectrophotometer. The feasibility of calibration transfer to a submersible, diode array equipment, to be subsequently operated in situ, was assessed using three procedures: slope and bias correction (SBC); single wavelength standardization (SWS) on mean spectra; and local centering (LC). The results showed that SBC was the most adequate for the available data, adding insignificant error to the base model estimates. Single wavelength standardization was a close second best, potentially more robust, and independent of the base iPLS model. Local centering was shown to be inadequate for the samples and instruments used.

O estudo apresentado neste trabalho teve como objetivo caracterizar experimentalmente o comportamento dinâmico de paredes de frontal Pombalino, simples e reforçadas, por meio de ensaios na mesa sísmica triaxial do Laboratório Nacional de Engenharia Civil. Os ensaios incidiram sobre dois modelos em escala real nos quais se reproduziu o comportamento de paredes de frontal pombalino, simulando dois andares. Os principais objetivos do trabalho foram: avaliar o desempenho sísmico de paredes de frontal pombalino sem reforço; avaliar o desempenho da técnica de reforço com chapas metálicas nos nós da estrutura de madeira; identificar algumas deficiências no comportamento sísmico dos edifícios pombalinos.

The equestrian statue of D. José I, in Lisbon, Portugal, stands on an elegant and decorated plinth fashioned in a very dense limestone. The sculptor, Joaquim Machado de Castro, designed the pedestal with colossal stone pieces and selected one of the best Portuguese stones for this purpose, the Lioz limestone. The same stone was also used for the flanking sculpture groups and the base This stone is a very pure reef limestone, rich in fossils and a low porosity <1%. It is extremely compact and highly resistant, even in the harsh environment of a busy metropolis and within the impact of marine winds. The generalized deterioration is surface erosion caused by direct runoff water, with some incipient black crusts and soiling incrustations occurring in sheltered places. In some areas copper stains originating from the metal statue were also found. Na extensive network of cracks was found,mostly at or near the top of the plinth, which could be ascribed to the presence of iron rods and clamps left inside the structure to hold the stone pieces together. During the intervention, these cracks were sealed with a multi-barrier system, given the impossibility to access the interior to remove or directly passivate the iron inclusions. Inoperative joints were cleaned out and repointed. Black deposits could be eliminated by nebulized water and soft brushing while the copper stains required the application of poultices with ammonium carbonate, in some cases requiring the addition of a complexing agent.

The equestrian statue of D. José I, in Lisbon, is a masterpiece of the sculptor Joaquim Machado de Castro. It weights over thirty eight tons and was made in a single casting by Bartolomeu da Costa in a copper alloy (brass). After over two centuries exposure, the statue presented an unappealing heterogenous appearance and showed some deterioration features that required attention. Preliminary studies showed that the deterioration phenomena were typical of copper alloys exposed to outdoor urban environments. The proximity of the seacoast also contributed to some specific decay mechanisms. The highly contrasting patterns of the superficial patinas consisted of black dense deposits covering a primitive cuprite layer side by side with the common green deposits of basic copper sulfates, hydroxides and chlorides. The highly corrosive nantokite was present in sheltered areas, where chlorides are able to accumulate. The conservation intervention included cleaning, mostly carried out with low pressure jets of round glass beads. Onsite tests were made to select the cleaning levels required to match the areas of black and green patinas. A reddish brown cuprite layer was found underneath most of the areas with black dense deposits, while it could only be perceived by transparency on the green covered areas. When a high contrast remained between the two areas, these were mitigated with the application of water colors during the final protection phase. Nantokite active areas were passivated with sodium oxalate after the entire statue was first washed with clean water and treated with lime water to leave an alkaline reserve to slow down the eventual corrosion process, and the sculpture rinsed with ethanol to accelerate its drying. The final protection was made with Paraloid B44 and microcrystalline waxes

This review focuses on cork as a natural, renewable and sustainable construction raw-material. Cork has an unusual combination of properties making it suitable for application in buildings and infrastructures, for example insulation, wear-resistance and durability. The material properties combined with a favourable ecological footprint allow designers, architects and engineers to meet some of the Green Building demands. A summary on cork production, structure, chemistry and properties was made. The processing into ork-based products, for example cork agglomerates and composites, is detailed as well as their properties and applications in construction. The aptitude of cork-based products for compliance with sustainability and energy efficiency criteria is also addressed.

The research study presented herein evaluates the corrosion behaviour of the reinforcing steel in blended concretes using two pozzolanic additives—metakaolin (MK) and silica fume (SF)—at 10% replacement of cement weight. They are exposed to CO2 and chlorides. The corrosion process was followed by monitoring of open-circuit potential (OCP), polarisation resistance (Rp) and electrochemical impedance spectroscopy (EIS). Electrochemical measurements show that the addition of MK and SF enhances corrosion resistance exposed to chlorides, however under accelerated carbonation these concretes show higher corrosion rates. In the simultaneous exposition to carbon dioxide and chlorides, SF-concrete shows a decrease of corrosion rate.

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This paper proposes a methodology for the prediction of the compressive creep strains of dam concrete based on wet-screened experimental results at constant elevated temperature conditions measured in situ. Due to its large aggregate dimensions, the experimental characterization of dam concrete has particular constraints. The wet-screened concrete, obtained by sieving the aggregates larger than a given dimension, after mixing, is used to cast standard specimens and to embed monitoring devices. An experimental in situ installation using creep cells was used to obtain the compressive creep strain development over time for the maturing conditions of the dam core. The study of the effect of wet-screening procedure on creep in compression considers three types of concrete, dam concrete and two wet-screened concretes tested at three loading ages, 28, 90 and 365 days. The comparison between different types of concrete at different maturing conditions requires the definition of a reference state given by the maturity method, using the equivalent age, and relies on the fit of compressive creep strains to the RILEM recommended model B3. To take into account the effect of the aggregate content on the deformability properties of dam concrete, an equivalent two-phase composite model was applied. The equivalent composite model considered the equivalent matrix as the wet-screened concrete and the inclusions as the larger aggregates that are removed during the wet-screening procedure. Predictions obtained with the composite model are close to the dam concrete experimental results, for the tested loading ages.