Artigos de Revista

Over the last two decades, remarkable progress in the Portuguese drinking water and wastewater services sector has been achieved. Nevertheless, it faces a serious challenge in trying to ensure long-term sustainability. There is equally scope for considerable efficiency and effectiveness gains. The national strategic plan for the period 2014

The aim of this experimental research was to study the electrochemical behavior of organic–inorganic hybrid (OIH) coatings for corrosion protection of hot-dip galvanized steel (HDGS) in the first instants of immersion in simulated concrete pore solution (SCPS) (pH > 12.5). The electrochemical performance of the OIH coatings was assessed by electrochemical impedance spectroscopy, potentiodynamic polarization curves, macrocell current density, and polarization resistance. The OIH coatings were prepared via the sol–gel method and were deposited on HDGS surfaces by dip-coating using one or three dip steps. The electrochemical results obtained for HDGS samples coated with OIH matrices in SCPS showed higher corrosion resistance than bare HDGS; as the molecular weight (MW) of Jeffamine® increased the barrier protection of the coating decreased. The lowest protection efficiency was found for HDGS samples synthesized with oligopolymers with an MW of 2000. Coatings produced with an oligopolymer of 230 MW conferred the highest protection. The surface morphology of the OIH coatings deposited on HDGS surfaces was studied by atomic force microscopy. The results show that the roughness of the OIH films depends on the MW of Jeffamine® and on the number of dip-coating steps used. Thermogravimetry results show that the Jeffamine® MW affected the thermal properties of the prepared OIH samples. The prepared OIH materials are thermally stable within the range of 20–80°C.

Corrosion degradation of materials and metallic structures is one of the major issues that give rise to depreciation of assets, causing great financial outlays in their recovery and or prevention. Therefore, the development of active corrosion protection systems for metallic substrates is an issue of prime importance. The promising properties and wide application range of hybrid sol?gel?derived polymers have attracted significant attention over recent decades. The combination of organic polymers and inorganic materials in a single phase provides exceptional possibilities to tailor electrical, optical, anticorrosive, and mechanical properties for diverse applications. This unlimited design concept has led to the development of hybrid coatings for several applications, such as transparent plastics, glasses, and metals to prevent these substrates from permeation, mechanical abrasion, and corrosion, or even for decorative functions. Nevertheless, the development of new hybrid products requires a basic understanding of the fundamental chemistry, as well as of the parameters that influence the processing techniques, which will briefly be discussed. Additionally, this review will also summarize and discuss the most promising sol?gel coatings for corrosion protection of steel, aluminium, and their alloysconducted at an academic level.

Corrosion degradation of materials and metallic structures is one of the major issues that give rise to depreciation of assets, causing great financial outlays in their recovery and or prevention. Therefore, the development of active corrosion protection systems for metallic substrates is an issue of prime importance. The promising properties and wide application range of hybrid sol-gel-derived polymers have attracted significant attention over recent decades. The combination of organic polymers and inorganic materials in a single phase provides exceptional possibilities to tailor electrical, optical, anticorrosive, and mechanical properties for diverse applications. This unlimited design concept has led to the development of hybrid coatings for several applications, such as transparent plastics, glasses, and metals to prevent these substrates from permeation, mechanical abrasion, and corrosion, or even for decorative functions. Nevertheless, the development of new hybrid products requires a basic understanding of the fundamental chemistry, as well as of the parameters that influence the processing techniques, which will briefly be discussed. Additionally, this review will also summarize and discuss the most promising sol-gel coatings for corrosion protection of steel, aluminium, and their alloys conducted at an academic level.

Wood plastic composites (WPCs) are being increasingly used as alternatives to wooden decks. In the presentstudy, it was verified the potential loss of stiffness of WPC deck boards as a result of moisture intake. It wasalso assessed the importance ofmoisture intake in the fulfilment of serviceability limit states. For these purposes, three different types of commercial WPC decks were studied, with high (WPCH), medium (WPCM) and low (WPCL) expected mechanical performance. Different experimental designs were followed to simulate full exposure to outdoor conditions and the effect of possible internal stress due to differential shrinkage and the swelling behaviour of fibres and the matrix. The results indicate a high loss of bendingmodulus of elasticity due to water absorption (between 40 and 50%) and shrinkage/swelling movements (between 22 and 29%). This level of stiffness loss has a direct impact on ensuring the compliance to the serviceability limit states. A strong negative linear relationship between water absorption and the loss of bending stiffness was established, which can be a helpful tool to assist manufacturers in defining the application rules and ensuring the expected service life of their products.

Water utilities are aware of the water-energy loss relevance in supply systems. However, they still mainly focus on daily water loss control (real and apparent losses), without considering the impact on embedded energy. Moreover, they are mostly concerned with the economic dimension and, in most cases, tend to disregard the impact that water-energy loss may have on the quality of service, communication with the consumers, social awareness, water quality and environment. This paper focuses on the application of the developed and tested AWARE-P IAM methodology to improve water-energy loss management in water supply systems, while demonstrating the main benefits from implementing an integrated approach for water losses and related energy assessment. Results show that indeed the participating iPerdas utilities were able to define tactical measures prone to a more efficient and sustainable service.

The susceptibility of bridge decks to vortex induced oscillations can b eaddressed through wind-tunnel testing. This paper considers the case of the Vila-Real Bridge, in the north of Portugal, which has the highest deck above ground (230m), among concrete-deck bridges cable-stayed in the central plane. It has a single-cell rectangular box girder with a wide top flange supported by regularly spaced inclined struts. Aeroelastic studies of this precise type of deck seem nonexistent in the literature.Results of sectional model tests are presented for a selection of three distinct angles of attack and three deck configurations, including a solution, alternative to the usual mitigation measures, that solved the susceptibility to vortex induced vibration of the deck and that has no relevant additional design or building costs.With the proposed approach, bridge designers may be able to relegate the use of sections with high aerodynamic performance

A procedure is proposed to assess the compatibility of cleaning actions to be carried out upon built heritage. This procedure was designed as a semi-quantitative (in)compatibility risk assessment, where the vulnerability of the substrate to cleaning, the aggressiveness of the cleaning method and the substrate/method synergies are factors considered to determine the likelihood of damage occurring, whereas the impact on the significance of the object measures the consequences of damage occurring. Rating these factors of likelihood and consequences of damage allows a cleaning risk matrix to be proposed for the evaluation of the risk levels implicated by different cleaning methods. Furthermore, planning components entirely contingent of their specific actors, and therefore inherently difficult to grade, such as operator skills or control adequacy, are included as quality components, which work as multiplying parameters of the overall risk. The procedure was conceived to assist in and frame the planning of built heritage cleaning actions. A Delphi Panel of conservation experts was convened to validate this proposal

The requirement to provide urban water services continuously while infrastructures are ageing, imposes the need for increasingly sustainable infrastructure asset management (IAM). To achieve and maintain adequate levels of service, the AWARE-P IAM methodology has been applied in collaborative projects launched by the National Civil Engineering Laboratory, in partnership with IST (Technical University of Lisbon), Addition (software company) and several water utilities.The objective of these projects is to support urban water utilities in the development, implementation and maintenance of IAM plans. To guarantee the success of IAM planning, following the AWARE-PIAM methodology, utilities are required to: consider that the infrastructure has system behaviour and lifespan is indefinite and guarantee the full-alignment of IAM planning with organisation objectives.By analysing the strategic and tactical plans of participating utilities, the proposed methodology principles are discussed and supported. The main innovation results from the implementation of IAM planning are also presented and discussed, including the challenges of setting up an IAM process, together with the major benefits and drawbacks that come up when developing IAM plans. The results were demonstrated by the effective implementation of 16 strategic and 14 tactical IAM plans by the participating utilities.